P.O. Box C • Jackrabbit Road • Nolanville, TX 76559 • 254.698.2233 • 800.762.9665 • Fax 254.698.2234
MATERIAL SAFETY DATA SHEET
Amerrock Products, LP Phone (254) 698 2233
# 1 Jackrabbit Rd Revised Date: May 30, 2003
Nolanville, TX 76559
MSDS #00004
SECTION I
PRODUCT IDENTIFICATION
PRODUCT: Granulated Products
“Premium Plus” ™ Foundation Insulation
SYNONYM: Insulation
CHEMICAL FAMILY: Slag wool fiber.
SECTION II
INGREDIENTS
______________________________________________
ACGIH OSHA
Material Wt(%) TLV PEL CAS
Mineral wool fiber
>84 mg/m3
10 mg/m3
15(T)/5 (R)
65997-17-3
Mineral oil <5 5 mist 5 mist
8012-95-1
Portland cement <15 10mg/m3 dust (t)10mg/m3(r)5mg/m3
85997-15-1
(T) – Total (R) – Respirable (NE) – Not Established
- OSHA and ACGIH recommended exposure level is 1 fiber/cc and NIOSH recommended exposure level is 3 fibers/cc. This material is slag wool. Other generic terms that are used or have been used to classify this material include mineral wool, stone wool, man-made mineral fiber (MMMF), and man-made vitreous fiber (MMVF). A more recent generic term that has appeared in the literature to describe these glass-like materials is synthetic vitreous fiber (SVF).
- Portland cement is made essentially of hydraulic calcium silicates contained in crystalline mass not separable into individual components. Substances known to be present are 3CaO.SiO2, 2CaO.SiO2, 3CaO.Al2O3, 4CaO.Al2O3Fe2O3, CaSO4XH2O. Small amounts of CaO, MgO, K2SO, Na2SO4 may be present.
SECTION III
HAZARD IDENTIFICATION
POTENTIAL HEALTH EFFECTS:
ACUTE: The primary component of this product is mineral wool fiber. During application or when dusty conditions exist, mineral wool fiber and cement dust may cause transitory mechanical irritation and caustic burns to skin, eyes or respiratory tract.
EYES: Direct contact with eye can cause mechanical irritation and chemical burns.
SKIN: This material (in wet state or as dust) is not chemically harmful if it gets on the skin and is immediately washed off. However direct contact of Portland cement dust and mineral wool fibers with skin can cause skin irritation (mechanical), itchiness and caustic burns.
INHALATION: Inhalation of dust can cause nose, throat, lungs and upper respiratory tract irritation. Persons exposed to dust may be forced to leave area because of nuisance conditions such as coughing, sneezing and nasal irritation and chemical burning.
INGESTION: If ingested drink plenty of water and contact a physician.
CHRONIC: Persons with chronic or systemic skin or eye disease should use precautions and wear all personal protective equipment when working with this product.
SECTION IV
FIRST AID MEASURES
EYES: In case of contact, immediately flush thoroughly with copious amounts of water occasionally lifting the lower and upper lids (to remove particulates). Get medical attention immediately. Contact lenses should not be worn working with this product.
SKIN: Skin contact is a chemical hazard with Portland cement. Wet cement can dry the skin and cause caustic burns. Mechanical action of fibers on skin can cause itchiness. Irritation of skin may occur with prolonged and repeated contact. Rinse with cool water, followed by washing with soap and warm water. A commercially available skin cream or lotion may be helpful to treat dry skin areas and apply sterile dressing. Wash hands before eating or using restroom.
INHALATION: If exposed to excessive levels of dust, leave area of dust exposure and remain away until coughing and other symptoms subside. Other measures are usually not necessary, however if conditions warrant, get medical attention.
INGESTION: If ingested drink plenty of water and contact a physician.
TARGET ORGANS: Eyes, skin, lungs and respiratory system.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED: Pre-exist-ing upper respiratory and lung disease such as, but not limited to, bronchitis, emphysema and asthma.
PRIMARY ROUTS OF ENTRY: Inhalation, eyes and skin contact.
Note to physician: This product is a mechanical irritant, and is not expected to produce any chronic health effects from acute exposures. Treatment should be directed toward removing the source of irritation with symptomatic treatment as necessary.
SECTION V
FIRE FIGHTING MEASURES
The products are none-combustible and do not pose a fire hazard. However, packing material may burn.
Extinguishing Media: Carbon dioxide (CO2), water, water fog, foam, dry chemical
Special Fire Fighting Procedures: No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to avoid inhalation of smoke and gases.
Unusual Fire and Explosion Hazards: None.
Special Fire Fighting Protective Equipment: Observe normal fire fighting procedures.
Flash Point (Method Used): Not applicable.
Upper and lower flammable limits in air: Not applicable.
Autoignition temperature: Not applicable.
Hazardous Combustion Products: Carbon dioxide, carbon monoxide and traces gases.
SECTION VI
ACCIDENTAL RELEASE MEASURES
CONTAINMENT: Not necessary. Treat as inert material.
CLEAN UP: Pick up large pieces. Use gloves to avoid skin irritation. Vacuum dust, preferably with an industrial vacuum cleaner with high efficiency air filiter. If sweeping is necessary, use dust suppressant such as water. Do not dry sweep dust accumulation or use compressed air for clean up. These procedures will help minimize potential exposures.
DISPOSAL: Dispose in sanitary landfill in accordance with local, state and federal requirements.
SECTION VII
HANDLING AND STORAGE
HANDLING: Use protective equipment to avoid irritation as described in Section 8.
STORRAGE: Warehouse storage should be in accordance with packing directions. Material should be kept dry and protected from the elements.
SECTION VIII
EXPOSURE CONTROL/PERSONAL PROTECTION
ENGINEERING CONTROLS: Provide general ventilation and local exhaust ventilation to meet TLV requirements of individual ingredients (see Section 2) and to control dusting conditions.
If cutting or trimming with power equipment, dust collectors and local ventilation should be used.
Avoid unnecessary exposure to dust and handle with care. Keep work area clean of dust and fibers by using an industrial vacuum cleaner with high efficiency filter or wetting down area with water. Never use compressed air and avoid dry sweeping.
EYE PROTECTION: Wear safety glasses with side shields or goggles to avoid eye irritation.
SKIN: Avoid prolonged contact with wet cement from application or perspiration. Workers should shower immediately with soap and water after prolonged contact. Cement burns with little warning because little heat is sensed.
RESPIRATORY PROTECTION: Wear a NIOSH/MSHA-approved dust respirator in poorly ventilated areas, where local exhaust is not feasible, if TLV is exceeded, and/or when dusty conditions exist.
OTHER CLOTHING: Wear tight fitting goggles and gloves when dusty conditions exist. Wear long-sleeved, loose fitting clothing at the neck and wrists and minimize skin contact. Wash work clothing separately from other clothing. Rinse washer thoroughly after use.
SECTION IX
PHYSICAL AND CHEMICAL PROPERTIES
• Appearance and Odor: Dark gray or tan-colored with White to off white in color with low odor
• Physical State: Solid
• Boiling: Not applicable
• Freezing Point: Not applicable
• Melting Point: 2100° F (1150° C)
• Specific Gravity (H20=1): Not applicable
• Solubility in Water: Insoluble
• ?H Range: Not applicable
• Vapor Pressure: Not applicable
• Evaporation Rate (in-Butyl Acetate=1): Not applicable
• Percent Volatile: Not applicable
• Volatile Organic Compounds: Not applicable
SECTION X
CHEMICAL STABILITY
STABILITY: Stable, Keep dry until used.
REACTIVITY: Not reactive
INCOMPATIBILITY: Acids, ammonium salts and phosphorous. (gives off H2S under certain acidic conditions).
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and smoke would be produced at high temperatures with thermal decomposition.
SECTION XI
TOXICOLOGICAL INFORMATION
ACUTE DATA:
SLAG WOOL FIBER (65997-17-3)
Oral LD50RAT: Not determined
Dermal LD50RAT: Not determined
Skin Irritation: Mechanical Irritant
Eye Irritation: Mechanical Irritant
Contact with mineral wool fibers may cause temporary eye and skin irritation (mechanical). When products are handled continually, the skin irritation generally diminishes.
Chronic Data: Inhalation: In October 2001, the International Agency for Research on Cancer (IARC) classified mineral wool fibers (rock or slag) as Group 3 (not classifiable as to carcinogenicity to humans).
SECTION XII
ECOLOGICAL INFORMATION
This product is not expected to have an adverse effect on the ecology.
SECTION XIII
DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of material in accordance with federal, state, and local regulations. Waters are not hazardous as defined by the Resource Conservation and Recovery Act (RCRA; 40 CFR 261).
WASTE NUMBERS: No EPA Waste Numbers are applicable for this product’s components.
SECTION XIV
TRANSPORT INFORMATION
- S. DOT INFORMATION: Not a hazardous material per DOT shipping requirements. Not classified or regulated.
SECTION XV
REGULATORY INFORMATION
CANADIAN REGULATIONS:
WHMIS: D28
All components of this product are included in the Canadian Domestic Substances List (DSL) or the Canadian Non-Domestic Substances List (NDSL).
USA REGULATIONS:
All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory.
CARCINOGENICITY CLASSIFICATION OF INGREDIENTS:
Material IARC NTP
Man Made Vitreous Fiber Group 3 None
Portland Cement Not Listed Not Listed
In October 2001, the International Agency for Research on Cancer (IARC) classified mineral wool fibers (rock or slag) as Group 3 (not classifiable as to carcinogenicity to humans). IARC noted specifically: “no evidence of increased risks of lung cancer or mesothelioma (cancer of the lining of the body cavities) from occupational exposures during manufacture of these materials, and inadequate evidence overall of any cancer risk.” This was a reversal of the IARC finding in 1987 of a Group 2B designation (possibly carcinogenic to humans) based on earlier studies in which animals were injected with large quantities of slag wool fibers.
Portland cement is not listed as a carcinogen by NTP, OSHA, or IARC. It may, however, contain trace amounts of substances listed as carcinogens by these organizations.
Crystalline silica, a potential trace level contaminant in Portland cement, is now classified by IARC as a known carcinogen (Group 1). NTP has characterized respirable silica as “reasonable anticipated to be (a) carcinogen”.
SECTION XVI
OTHER INFORMATION
INFORMATION FOR HANDLING AND IDENTIFICATION OF CHEMICAL HAZARDS
NFPA Ratings: Health: 0 Fire: 1 Reactivity: 1 Other: N/A
HMIS Ratings: Health: 0 Fire: 1 Reactivity: 1
Personal Protection: Use eye and skin protection. Use NIOSH/MSHA – approved respiratory protection when necessary.
0 = Minimal Hazard 1 = Slight Hazard 2 = Moderate Hazard
3 = Serious Hazard 4 = Severe Hazard
? CAUTION:
Dust exposure can cause temporary eye, skin and respiratory tract irritation. Avoid creating dust and install in well ventilated area. Cut and trim with razor knife or hand saw to minimize dust levels. Using power tools for cutting will generate high dust levels. Power tools should be equipped with dust collection system. Use NIOSH/MSHA- approved dust respirator. Avoid dust contact with eyes and skin. Wear eye protection and long-sleeve, loose fitting clothing closed at the neck and wrists. Wash work clothing separately from other clothing. Rinse washer thoroughly.
KEEP OUT OF REACH CHILDERN
THIS PRODUCT CONTAINS NO ASBESTOS
FIRST AID: For skin irritation, rinse skin with cool water, followed by washing with soap and warm water. A commercially available skin cream or lotion may be helpful to treat dry skin areas and apply sterile dressing. For eye irritation, flush eyes thoroughly with water for 15 minutes. If irritation continues, or product is swallowed, consult a physician.
Key/Legend
ACGIH American Conference of Government Industrial Hygienists
CAS Chemical Abstracts Service (Registry Number)
DOT United States Department of Transportation
EPA United States Environmental Protection Agency
HMIS Hazardous Materials Identification System
IARC International Agency for Research on Cancer
MSDS Material Safety Data Sheet
MSHA Mine Safety and Health Administration
NFPA National Fire Protection Association
NIOSH National Institute for Occupational Safety & Health
NTP National Toxicology Program
OSHA Occupational Health and Safety Administration
PEL Permissible Exposure Limit
TLV Threshold Limit Value
TF936 11/03 Printed in USA
©2007 Amerrock Products LP